Scientific References

Peer Reviewed Literature: Local- and regional-scale measurements of CH4, d13CH4, and C2H6 in the Uintah Basin using a mobile stable isotope analyzer

Authors C. W. Rella, J. Hoffnagle, Y. He, and S. Tajima
Date October 30th, 2015


In this paper, we present an innovative CH4, 13CH4, and C2H6 instrument based on cavity ring-down spectroscopy (CRDS). The design and performance of the analyzer is presented in detail. The instrument is capable of precision of less than 1‰ on 13CH4 with 1 in. of averaging and about 0.1‰ in an hour. Using this instrument, we present a comprehensive approach to atmospheric methane emissions attribution. Field measurements were performed in the Uintah Basin (Utah, USA) in the winter of 2013, using a mobile lab equipped with the CRDS analyzer, a highaccuracy GPS, a sonic anemometer, and an onboard gas storage and playback system.With a small population and almost no other sources of methane and ethane other than oil and gas extraction activities, the Uintah Basin represents an ideal location to investigate and validate new measurement methods of atmospheric methane and ethane.We present the results of measurements of the individual fugitive emissions from 23 natural gas wells and six oil wells in the region. The 13CH4 and C2H6 signatures that we observe are consistent with the signatures of the gases found in the wells. Furthermore, regional measurements of the atmospheric CH4, 13CH4, and C2H6 signatures throughout the basin have been made, using continuous sampling into a 450m long tube and laboratory reanalysis with the CRDS instrument. These measurements suggest that 857% of the total emissions in the basin are from natural gas production.